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Effect of temperature on Lu’an bituminous char structure evolution in pyrolysis and combustion

Yandi ZHANG, Yinhe LIU, Xiaoli DUAN, Yao ZHOU, Xiaoqian LIU, Shijin XU

《能源前沿（英文）》 2021年 第15卷 第1期   页码 14-25 doi: 10.1007/s11708-020-0805-x

摘要： In the process of pyrolysis and combustion of coal particles, coal structure evolution will be affected by the ash behavior, which will further affect the char reactivity, especially in the ash melting temperature zone. Lu’an bituminous char and ash samples were prepared at the N and air atmospheres respectively across ash melting temperature. A scanning electron microscope (SEM) was used to observe the morphology of char and ash. The specific surface area (SSA) analyzer and thermogravimetric analyzer were respectively adopted to obtain the pore structure characteristics of the coal chars and combustion parameters. Besides, an X-ray diffractometer (XRD) was applied to investigate the graphitization degree of coal chars prepared at different pyrolysis temperatures. The SEM results indicated that the number density and physical dimension of ash spheres exuded from the char particles both gradually increased with the increasing temperature, thus the coalescence of ash spheres could be observed obviously above 1100°C. Some flocculent materials appeared on the surface of the char particles at 1300°C, and it could be speculated that -Si N was generated in the pyrolysis process under N . The SSA of the chars decreased with the increasing pyrolysis temperature. Inside the char particles, the micropore area and its proportion in the SSA also declined as the pyrolysis temperature increased. Furthermore, the constantly increasing pyrolysis temperature also caused the reactivity of char decrease, which is consistent with the results obtained by XRD. The higher combustion temperature resulted in the lower porosity and more fragments of the ash.

关键词： bituminous char     pyrolysis     ash     structure evolution     reactivity    

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Tuning the electronic structure of NiCoP arrays through V doping for pH-universal hydrogen evolution

Yu Lin, Jinlei Wang, Duanlin Cao, Yaqiong Gong

《化学科学与工程前沿（英文）》 2021年 第15卷 第5期   页码 1134-1146 doi: 10.1007/s11705-020-2014-x

摘要： The exploration of cost-effective, high-performance, and stable electrocatalysts for the hydrogen evolution reaction (HER) over wide pH range (0–14) is of paramount importance for future renewable energy conversion technologies. Regulation of electronic structure through doping vanadium atoms is a feasible construction strategy to enhance catalytic activities, electron transfer capability, and stability of the HER electrode. Herein, V-doped NiCoP nanosheets on carbon fiber paper (CFP) (denoted as V -NiCoP/CFP) were constructed by doping V modulation on NiCoP nanosheets on CFP and used for pH-universal HER. Benefiting from the abundant catalytic sites and optimized hydrogen binding thermodynamics, the resultant V -NiCoP/CFP demonstrates a significantly improved HER catalytic activity, requiring overpotentials of 46.5, 52.4, and 85.3 mV to reach a current density of 10 mA·cm in 1 mol·L KOH, 0.5 mol·L H SO , and 1 mol·L phosphate buffer solution (PBS) electrolytes, respectively. This proposed cation-doping strategy provides a new inspiration to rationally enhance or design new-type nonprecious metal-based, highly efficient, and pH-universal electrocatalysts for various energy conversion systems.

关键词： hydrogen evolution reaction     transition metal phosphides     pH-universal     vanadium doping     carbon fiber paper    

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非规则时序信息的结构转换及演化的细化分析

欧阳首承,张葵,郝丽萍,周莉蓉

《中国工程科学》 2005年 第7卷 第4期   页码 36-41

摘要：

按时间不占有物质维的概念，将时序性自动信息转换为结构信息。结果显示自动信息的非规则可用于降水的细化预测，也为更广泛的演化非规则信息提供了可应用的方法，充分地说明了气象问题是演化科学的问题，或者说将其理解为牛顿的惯性系领域的分支科学是有待商榷的。

关键词： 时序信息     细化     结构非规则     方位相空间     演化    

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Enhanced methane recovery and exoelectrogen-methanogen evolution from low-strength wastewater in an up-flow

Zechong Guo, Lei Gao, Ling Wang, Wenzong Liu, Aijie Wang

《环境科学与工程前沿（英文）》 2018年 第12卷 第4期 doi: 10.1007/s11783-018-1074-3

摘要：

Methane yield increased 22 times from low-strength wastewater by applying conductive fillers.

Conductive fillers accelerated the start-up stage of anaerobic biofilm reactor.

Conductive fillers altered methanogens structure.

关键词： Low-strength wastewater     Methane production     Conductive filler     Microbial community structure    

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Tuned reactive power dispatch through modified differential evolution technique

S. BISWAS (RAHA), N. CHAKRABORTY

《能源前沿（英文）》 2012年 第6卷 第2期   页码 138-147 doi: 10.1007/s11708-012-0188-8

摘要： This paper explores the capability of modified differential evolution (MDE) technique for solving the reactive power dispatch (RPD) problem. The proposed method is based on the basic differential evolution (DE) technique with a few modifications made into it. DE is one of the strongest optimization techniques though it suffers from the problem of slow convergence while global minima appear. The proposed modifications are tried to resolve the problem. The RPD problem mainly defines loss minimization with stable voltage profile. To solve the RPD problem, the generator bus voltage, transformer tap setting and shunt capacitor placements are controlled by the MDE approach. In this paper, IEEE 14-bus and IEEE 30-bus systems are chosen for MDE implementation. The applied modification show much improved result in comparison to normal DE technique. Comparative study with other soft-computing technique including DE validates the effectiveness of the proposed method.

关键词： reactive power dispatch (RPD)     modified differential evolution (MDE)     differential evolution algorithm with localizations around the best vector (DELB)    

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Strategic Thinking on a Revolution/an Evolution in Production and Consumption of Energy in China

Ke-chang Xie,Ke Liu

《工程管理前沿（英文）》 2014年 第1卷 第1期   页码 30-36 doi: 10.15302/J-FEM-2014006

摘要： This article summarizes the thinking behind the call for a revolution/an evolution in China's energy production and consumption. China is still a developing country, though it has experienced fast economic growth in the past thirty years. It achieved great accomplishments surprising the world, and it is also confronted with challenges on energy supply and environmental protection. As environmental pollution becomes more and more serious, the energy challenges have become more and more complicated. With this in mind, the authors analyzed China's energy situation, China's energy supply and consumption, the world energy map, China's commitment both to improving its domestic environment and fulfilling its international obligations to control climate change. Action plans are presented to support the call for a revolution/an evolution in China's energy production and consumption as an effective assurance for China's ambitious goal of building a moderately prosperous society in all respects.

关键词： revolution     evolution     energy     production     consumption    

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Polypyrrole@NiCo hybrid nanotube arrays as high performance electrocatalyst for hydrogen evolution reaction

Shenghua Ye, Gaoren Li

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 473-480 doi: 10.1007/s11705-018-1724-9

摘要：

The polypyrrole(PPy)@NiCo hybrid nanotube arrays have been successfully fabricated as a high performance electrocatalyst for hydrogen evolution reaction (HER) in alkaline solution. The strong electronic interactions between PPy and NiCo alloy are confirmed by X-ray photoelectron spectroscopy and Raman spectra. Because these interations can remarkably reduce the apparent activation energy (Ea) for HER and enhance the turnover frequency of catalysts, the electrocatalytic performance of PPy@NiCo hybrid nanotube arrays are significantly improved. The electrochemical tests show that the PPy@NiCo hybrid catalysts exhibit a low overpotential of ~186 mV at 10.0 mA·cm−2 and a small tafel slope of 88.6 mV·deg−1 for HER in the alkaline solution. The PPy@NiCo hybrid nanotubes also exhibit high catalytic activity and high stability for HER.

关键词： NiCo alloy     polypyrrole     hybrid nanotube     electrocatalyst     hydrogen evolution reaction    

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Synergistic effect of V and Fe in Ni/Fe/V ternary layered double hydroxides for efficient and durable oxygen evolution

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 102-115 doi: 10.1007/s11705-022-2179-6

摘要： High-performance and stable electrocatalysts are vital for the oxygen evolution reaction (OER). Herein, via a one-pot hydrothermal method, Ni/Fe/V ternary layered double hydroxides (NiFeV-LDH) derived from Ni foam are fabricated to work as highly active and durable electrocatalysts for OER. By changing the feeding ratio of Fe and V salts, the prepared ternary hydroxides were optimized. At an Fe:V ratio of 0.5:0.5, NiFeV-LDH exhibits outstanding OER activity superior to that of the binary hydroxides, requiring overpotentials of 269 and 274 mV at 50 mA·cm–2 in the linear sweep voltammetry and sampled current voltammetry measurements, respectively. Importantly, NiFeV-LDH shows extraordinary long-term stability (≥ 75 h) at an extremely high current density of 200 mA·cm–2. In contrast, the binary hydroxides present quick decay at 200 mA·cm–2 or even reduced current densities (150 and 100 mA·cm–2). The outstanding OER performance of NiFeV-LDH benefits from the synergistic effect of V and Fe while doping the third metal into bimetallic hydroxide layers: (a) Fe plays a crucial role as the active site; (b) electron-withdrawing V stabilizes the high valence state of Fe, thus accelerating the OER process; (c) V further offers great stabilization for the formed intermediate of FeOOH, thus achieving superior durability.

关键词： oxygen evolution reaction     electrocatalysts     ternary layered double hydroxides     long-term stability    

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动态组织可持续性分析及在世博会国际建设协调中的应用研究

施骞,卢昱杰,乐云

《中国工程科学》 2010年 第12卷 第1期   页码 108-112

摘要：

通过分析世博会项目管理的目标体系，揭示了国际参展协调工作所面临的挑战。并以直线制、直线职能制和矩阵制组织结构为基础，结合上海世博会国际参展协调工作的特点，兼顾组织运行效率、组织成本和人力资源配置等组织设计的影响因素，提出了动态演进式的组织结构优化模式。

关键词： 上海世博会     动态演进式组织结构     项目管理    

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heterostructure grown on nickel foam as efficient and durable self-supported electrocatalysts for hydrogen evolution

《化学科学与工程前沿（英文）》 2023年 第17卷 第4期   页码 437-448 doi: 10.1007/s11705-022-2228-1

摘要： High-performance and ultra-durable electrocatalysts are vital for hydrogen evolution reaction (HER) during water splitting. Herein, by one-pot solvothermal method, MoOx/Ni3S2 spheres comprising Ni3S2 nanoparticles inside and oxygen-deficient amorphous MoOx outside in situ grow on Ni foam (NF), to assembly the heterostructure composites of MoOx/Ni3S2/NF. By adjusting volume ratio of the solvents of ethanol to water, the optimized MoOx/Ni3S2/NF-11 exhibits the best HER performance, requiring an extremely low overpotential of 76 mV to achieve the current density of 10 mA∙cm‒2 (η10 = 76 mV) and an ultra-small Tafel slope of 46 mV∙dec‒1 in 0.5 mol∙L‒1 H2SO4. More importantly, the catalyst shows prominent high catalytic stability for HER (> 100 h). The acid-resistant MoOx wraps the inside Ni3S2/NF to ensure the high stability of the catalyst under acidic conditions. Density functional theory calculations confirm that the existing oxygen vacancy and MoOx/Ni3S2 heterostructure are both beneficial to the reduced Gibbs free energy of hydrogen adsorption (|∆GH*|) over Mo sites, which act as main active sites. The heterostructure effectively decreases the formation energy of O vacancy, leading to surface reconstruction of the catalyst, further improving HER performance. The MoOx/Ni3S2/NF is promising to serve as a highly effective and durable electrocatalyst toward HER.

关键词： molybdenum oxides     oxygen vacancies     heterostructure     electrocatalysts     hydrogen evolution reaction    

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Innovation evolution of China’s high-speed rail industry

Jin CHEN, Liang MEI

《工程管理前沿（英文）》 2018年 第5卷 第4期   页码 548-552 doi: 10.15302/J-FEM-2018208

摘要：
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The International Conference on the Evolution of China Urban Water Environment & Ecology, 2019

Jiuhui Qu

《环境科学与工程前沿（英文）》 2019年 第13卷 第6期 doi: 10.1007/s11783-019-1179-3

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High-entropy catalysts for electrochemical water-electrolysis of hydrogen evolution and oxygen evolution

《能源前沿（英文）》 doi: 10.1007/s11708-023-0892-6

摘要： High entropy materials (HEMs) have developed rapidly in the field of electrocatalytic water-electrolysis for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) due to their unique properties. In particular, HEM catalysts are composed of many elements. Therefore, they have rich active sites and enhanced entropy stability relative to single atoms. In this paper, the preparation strategies and applications of HEM catalysts in electrochemical water-electrolysis are reviewed to explore the stabilization of HEMs and their catalytic mechanisms as well as their application in support green hydrogen production. First, the concept and four characteristics of HEMs are introduced based on entropy and composition. Then, synthetic strategies of HEM catalysts are systematically reviewed in terms of the categories of bottom-up and top-down. The application of HEMs as catalysts for electrochemical water-electrolysis in recent years is emphatically discussed, and the mechanisms of improving the performance of electrocatalysis is expounded by combining theoretical calculation technology and ex-situ/in situ characterization experiments. Finally, the application prospect of HEMs is proposed to conquer the challenges in HEM catalyst fabrications and applications.

关键词： high-entropy     electrocatalysis     synthetic methods     water-electrolysis     hydrogen and oxygen evolutions    

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Interspecies transmission and evolution of the emerging coronaviruses: perspectives from bat physiologyand protein spatial structure

Baicheng HUANG, Kegong TIAN

《农业科学与工程前沿（英文）》 2020年 第7卷 第2期   页码 218-226 doi: 10.15302/J-FASE-2020324

摘要：

Emergent coronaviruses (CoVs) such as SARS-CoV and MERS-CoV have posed great threats to public health worldwide over the past two decades. Currently, the emergence of SARS-CoV-2 as a pandemic causes greater public health concern. CoV diversity is due to the large size and replication mechanisms of the genomes together with having bats as their optimum natural hosts. The ecological behavior and unique immune characteristics of bats are optimal for the homologous recombination of CoVs. The relationship of spatial structural characteristics of the spike protein, a protein that is critical for recognition by host receptors, in different CoVs may provide evidence in explaining the coevolution of CoVs and their hosts. This information may help to enhance our understanding of CoV evolution and thus provide part of the basis of preparations for any future outbreaks.

关键词： bat     coronavirus     evolution     host receptor     spike protein     transmission    

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Organizational evolution of project management teams over the whole lifecycle of megaprojects: Case study

《工程管理前沿（英文）》   页码 439-454 doi: 10.1007/s42524-022-0211-7

摘要： Project management teams are critical in the implementation of megaprojects, but their evolution throughout the project lifecycle has not been clearly explained. This paper explores the organizational evolution of megaproject management teams through a longitudinal retrospective case study of the Hong Kong–Zhuhai–Macao Bridge (HZMB) project. The organizational evolution is examined in terms of management objectives, management content, and organizational structure. The organizational evolution of the HZMB project management team exhibits stage differentiation with the coexistence of turbulence and stability. Changes in the external environment are the driving force for organizational evolution, whereas a flexible organizational strategy is critical in promoting this evolution. Basing on the HZMB case study, this paper summarizes six critical measures that facilitate the organizational evolution of megaproject management teams. Our findings add value to megaproject management theory and provide a better understanding of the dynamics and complexity of megaproject organizational management.

关键词： megaproject     organizational evolution     whole lifecycle management     project management team    

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标题 作者 时间 类型 操作

Effect of temperature on Lu’an bituminous char structure evolution in pyrolysis and combustion

Yandi ZHANG, Yinhe LIU, Xiaoli DUAN, Yao ZHOU, Xiaoqian LIU, Shijin XU

期刊论文

Tuning the electronic structure of NiCoP arrays through V doping for pH-universal hydrogen evolution

Yu Lin, Jinlei Wang, Duanlin Cao, Yaqiong Gong

期刊论文

非规则时序信息的结构转换及演化的细化分析

欧阳首承,张葵,郝丽萍,周莉蓉

期刊论文

Enhanced methane recovery and exoelectrogen-methanogen evolution from low-strength wastewater in an up-flow

Zechong Guo, Lei Gao, Ling Wang, Wenzong Liu, Aijie Wang

期刊论文

Tuned reactive power dispatch through modified differential evolution technique

S. BISWAS (RAHA), N. CHAKRABORTY

期刊论文

Strategic Thinking on a Revolution/an Evolution in Production and Consumption of Energy in China

Ke-chang Xie,Ke Liu

期刊论文

Polypyrrole@NiCo hybrid nanotube arrays as high performance electrocatalyst for hydrogen evolution reaction

Shenghua Ye, Gaoren Li

期刊论文

Synergistic effect of V and Fe in Ni/Fe/V ternary layered double hydroxides for efficient and durable oxygen evolution

期刊论文

动态组织可持续性分析及在世博会国际建设协调中的应用研究

施骞,卢昱杰,乐云

期刊论文

heterostructure grown on nickel foam as efficient and durable self-supported electrocatalysts for hydrogen evolution

期刊论文

Innovation evolution of China’s high-speed rail industry

Jin CHEN, Liang MEI

期刊论文

The International Conference on the Evolution of China Urban Water Environment & Ecology, 2019

Jiuhui Qu

期刊论文

High-entropy catalysts for electrochemical water-electrolysis of hydrogen evolution and oxygen evolution

期刊论文

Interspecies transmission and evolution of the emerging coronaviruses: perspectives from bat physiologyand protein spatial structure

Baicheng HUANG, Kegong TIAN

期刊论文

Organizational evolution of project management teams over the whole lifecycle of megaprojects: Case study

期刊论文